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picture1_23141 Item Download 2022-09-09 19-01-02


picture2_23141 Item Download 2022-09-09 19-01-02 picture3_23141 Item Download 2022-09-09 19-01-02

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File: 23141 Item Download 2022-09-09 19-01-02
Some Diels-Alder Reactions in water solution 1. Faster in water than in other solvents. 2. Even in a case in which reaction is faster in isooctane than in methanol. 3 ...

icon picture PPT Filetype Power Point PPT | Posted on 09 Sep 2022 | 2 years ago
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...Some diels alder reactions in water solution faster than other solvents even a case which reaction is isooctane methanol speeds with additives that increase the hydrophobic effect licl but slows an antihydrophobic additive guanidinium chloride more selective for endo addition and on aqueous solutions suspensions r breslow u maitra d rideout tetrahedron lett abstract show high exo selectivities considerable layer of neat diene dienophile suggest much occurs or at phase this consistent our rough rate measurements thus as medium processes practical interest poorly soluble substrates effects simple organic acts chem res interestingly preference was found cyclopentadiene over undissolved selectivity produced by packing reagents substrate o h oh li rbh so b ratio m cd od ph c f mark biiscoe christopher uyeda rb org considerations choosing oxidant t s geometry peracid dioxirane not permitted transition state houk k n liu j demello condroski am soc...
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