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...St nd law and in a simple system du q pdv tds p ds dv qtds t the functions u s v n are called fundamental equations of each one them contains full information about generally ydx energy representation i y dx entropy state intensive variables written as extensive for fixed mole numbers x chemical potential partial molar quantities m component quasi static work w dn c quantity is an function associated with when constant volume ji j euler relation both homogeneous first order parameters xi l let uts pv supv systems gibbs duhem pvn dud ts d ini td idni sdt vdpnidi ud vd single vdp...